Material Safety Data Sheet Hazardous according to the criteria of Worksafe Australia
1. IDENTIFICATION
Product Name:
14 Garling Rd. Kings Park, 2148 NSW Australia
Emergency Telephone Number: No emergency telephone number available. 2. HAZARDS IDENTIFICATION
Based on the available information, not classified as hazardous according to the criteria of Worksafe Australia. The unodourised gas contains less than 0.1% of 1, 3 Butadiene and is not classified as hazardous . Classified as Dangerous Goods Class 2.1, by the criteria of the Australian Dangerous Goods Code for transport by road and rail. F+ Extremely Flammable Xn: Harmful R65:May cause lung damage if swallowed R66: Repeated exposure may cause skin dryness or cracking. S2: keep out of reach of Children S23:Do not breath spray S24/25
S26:In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. Phone 13 11 26. S62: If swallowed do NOT induce vomiting, seek medical advice immediately(contact a doctor or Poisons Information Centre. Phone 13 11 26) and show this container or label.
3. COMPOSITION/INFORMATION ON INGREDIENTS
All the constituents of this material are listed on the Australian Inventory of Chemical Substances 4. FIRST AID MEASURES
Skin:
Wash contaminated skin with plenty of soap and water. Remove contaminated clothing and wash before re-use. If irritation occurs seek medical advice.
Eyes: Irrigate with copious amounts of water for 15 minutes. In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. Phone 13 11 26. Inhalation: Remove victim from exposure – avoid becoming a casualty. Allow patient to
assume most comfortable position and keep warm. Keep at rest until fully recovered. If breathing is laboured and patient cyanotic (blue), ensure airways are clear and have a qualified person give oxygen through facemask. If breathing has stopped, apply artificial respiration at once. In event of cardiac arrest, apply external cardiac massage. Seek medical advice.
Ingestion:
Give a little water to drink. Do NOT induce vomiting. Avoid giving milks, oils or alcohol. Seek medical advice
Advice to doctor – treat symptomatically. 5. FIRE FIGHTING MEASURES
Specific hazards:
Aerosol cans may rupture or explode when exposed to temperatures above
50ºC. Propellant is extremely flammable and heavier than air. Do not allow vapours to build up in pits or hollows. Fire fighting further advice: Fight fire from protected position or use unmanned hose holders or monitor nozzles. If safe to do so, move undamaged containers from fire area. Do not approach hot containers. Cool containers with water before handling. If impossible to extinguish fire, protect surroundings, withdraw from area and allow fire to burn Fire-fighters to wear self-contained breathing apparatus (SCBA) and protective gloves. Structural fire-fighter’s uniform provides limited protection. Suitable extinguishing media: For small fires use water spray, dry chemical or carbon dioxide
6. ACCIDENTAL RELEASE MEASURES
Eliminate all sources of ignition. Contain spill for disposal. Add absorbent (sand, earth, sawdust, etc.) to spill area. Keep out of drains and waterways. Dispose of adsorbed material at an approved disposal site according to local government regulations. Ventilate confined spaces well. 7. HANDLING AND STORAGE
Storage:
Store away from oxidising agents. Do not store above 50ºC. Do NOT allow cartons to become wet.
Classified as Class 2.1(Aerosols) for the purpose of storage and handling, in accordance with the requirements of AS 2278. Refer to State and Territory Dangerous Goods regulations. Handling: Label states: “NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER CONTRARY TO THIS LABEL UNLESS AUTHORISED. WARNING: Do not deliberately sniff this product, sniffing may harm or kill you. CAUTION: HIGHLY FLAMMABLE: Pressurised dispenser. Do not use near fire or flame. No smoking. Do not spray directly on humans, pets, exposed food, food preparation areas or food utensils. Remove or cover fish tanks before use. Keep spray away from eyes. Keep in a cool place out of the sun and out of reach of children. Store below 50ºC. Do not incinerate or puncture this can, even when empty. Dispose of can by putting in garbage or leaving at an appropriate metal recycling collection point 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
National occupational exposure limits The assigned value for this product is TWA 1200 mg/cubic meter (171ppm) as per MSDS for Solvent . Propane is an Asphyxiant. Butane TWA is 800 ppm Engineering measures Use explosion proof equipment. Use only in a well ventilated area. Do NOT use near naked flames. Personal Protection At all times protect eyes and avoid direct contact with eyes. In a work environment wear gloves. Flammability Use in well ventilated areas. Do NOT use near ignition sources. 9. PHYSICAL AND CHEMICAL PROPERTIES Use:
Surface spray for killing crawling insects
Dispenses as an aerosol spray into a clear, straw-coloured liquid with a lemon odour
10. STABILITY AND REACTIVITY
Propellant can react with oxidising agents – chlorine, pool chlorine and nitric acid. Store away from oxygen cylinders, oxidising materials and ignition sources. 11. TOXICOLOGICAL INFORMATION
No adverse health effects are expected if the product is handled in accordance with this Safety Data sheet and product label. Label states: “NOT TO BE USED FOR ANY PURPOSE, OR IN ANY MANNER CONTRARY TO THIS LABEL UNLESS AUTHORISED. WARNING: Do not deliberately sniff this product, sniffing may harm or kill you. CAUTION: HIGHLY FLAMMABLE: Pressurised dispenser. Do not use near fire or flame. No smoking. Do not spray directly on humans, pets, exposed food, food preparation areas or food utensils. Remove or cover fish tanks before use. Keep spray away from eyes. STORAGE AND DISPOSAL: Keep in a cool place out of the sun and out of reach of children. Store below 50ºC. Do not incinerate or puncture this can, even when empty. Dispose of can by putting in garbage or leaving at an appropriate metal recycling collection point. FIRST AID: If poisoning occurs contact a doctor or Poisons Information Centre (Phone 131 126). If sprayed on skin, wash thoroughly. If sprayed in mouth rinse with water.” Acute Effects Skin contact: Contact with skin may result in mild irritation Eye contact: An eye irritant Inhalation: Vapour is a mild irritant. Inhalation of vapour can result in headaches, dizziness
and possible nausea. Inhalation of high concentrations can produce central nervous system depression, which can lead to loss of coordination and impaired judgement.
Ingestion:
Ingestion can result in nausea, vomiting and diarrhoea.
Chronic Effects No chronic systemic effects reported from industrial exposures. Carcinogenicity, Mutigenicity, Teratogenicity : No Known effect. 12. ECOLOGICAL INFORMATION Avoid contaminating waterways, product his harmful to aquatic organisms and the environment. 13. DISPOSAL CONSIDERATIONS Aerosols should be completely empty before disposing. Recycle can if a facility is available or place can in household rubbish Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code for transp ORT I Rail. NFORMATION
UN Proper Shipping Name: Aerosols Class and Subsidiary Risk: 2.1 Packing Group:
Do not allow cartons to become wet. Do not store above 50ºC. 15. REGULATORY INFORMATION Hazard Category:
Xn Xi F+ Extremely Flammable Xn: Harmful R65:May cause lung damage if swallowed (highly unlikely in an aerosol form) R66: Repeated exposure may cause skin dryness or cracking. S2: keep out of reach of Children S23:Do not breath spray S24/25
S26:In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. Phone 13 11 26. S62: If swallowed do NOT induce vomiting, seek medical advice immediately(contact a doctor or Poisons Information Centre. Phone 13 11 26) and show this container or label. Classified as Hazardous Goods by the criteria of Worksafe Australia Poisons Schedule (Aust)/Toxic Substance (NZ):
APVMA No 46433 16. OTHER INFORMATION This MSDS summarises at the date if issue our best knowledge of the health and safety hazard information of this product. Although this information is presented in good faith and compiled from various sources,( for example and where applicable from Raw material MSDS, List of material compiled by the Australian Government Hazardous Substance Information System, Standard for the Uniform Scheduling of Drugs and Poisons, Australian Dangerous Good Code for Road and Rail, Australian Pesticides and Veterinary Medicine labelling code for Agricultural Products, Environmental Risk Management Authority (ERMA) New Zealand Group Code Standards for Aerosols NZ, Food Standards Australia and New Zealand labelling and other Information Requirements ), believed to be accurate, Multi-Fill Pty Ltd make no representations or warranty as to the completeness or accuracy thereof. If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company. CONTACT POINT:
Multi-Fill Pty Ltd Technical Manager (02) 9621 6000
PREPARED BY: APPROVED BY:
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