ROCOL CHAIN AND DRIVE SPRAY Chemwatch Material Safety Data Sheet Issue Date: 16-Jun-2006 CHEMWATCH 214465 XCC317SCP Version No:3 CD 2007/3 Page 1 of 7 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME ROCOL CHAIN AND DRIVE SPRAY SYNONYMS "mineral oil spray aerosol lubricant" PROPER SHIPPING NAME AEROSOLS PRODUCT USE The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing. Before starting consider control of exposure by mechanical ventilation. Lubricant for chains and drives. Flammable solvent evaporates to leave lubricant coating. Application is by spray atomisation from a hand held aerosol pack. SUPPLIER Company:ITW Polymers& Fluids Company:ITW Polymers& Fluids NZ Address: Address: 100 Hassall St Unit 2 / 38 Trugood Drive Wetherill Park NSW 2164 East Tamaki, Auckland,2013 Australia New Zealand Telephone:(02) 9757 8800 Telephone:(09) 272 1945 EmergencyTel: (02) 9757 8800 EmergencyTel: (09) 272 1945 Fax: (02) 9757 3855 Fax: (09) 273 6489 Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. POISONS SCHEDULE
Risk of explosion if heated under confinement.
Harmful: danger of serious damage to health by prolongedexposure through inhalation.
Toxic to aquatic organisms may cause long- term adverseeffects in the aquatic environment.
Possible risk of impaired fertility.
Vapours may cause drowsiness and dizziness.
Keep away from sources of ignition. No smoking.
Do not breathe gas/ fumes/ vapour/ spray.
Keep container in a well ventilated place.
Avoid exposure - obtain special instructions before use.
To clean the floor and all objects contaminated by thismaterial use water and detergent.
This material and its container must be disposed of in asafe way.
Keep away from food drink and animal feeding stuffs.
Take off immediately all contaminated clothing.
If swallowed IMMEDIATELY contact Doctor or PoisonsInformation Centre (show this container or label). continued. ROCOL CHAIN AND DRIVE SPRAY Chemwatch Material Safety Data Sheet Issue Date: 16-Jun-2006 CHEMWATCH 214465 XCC317SCP Version No:3 CD 2007/3 Page 2 of 7 Section 2 - HAZARDS IDENTIFICATION
Use appropriate container to avoid environmentcontamination.
Avoid release to the environment. Refer to specialinstructions/ safety data sheets.
This material and its container must be disposed of ashazardous waste. Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
solvent naphtha petroleum, light aliphatic
Section 4 - FIRST AID MEASURES SWALLOWED Not considered a normal route of entry. If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus. · If swallowed do NOT induce vomiting. · If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Avoid giving milk or oils. Avoid giving alcohol. If aerosols come in contact with the eyes: · Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water. · Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. If solids or aerosol mists are deposited upon the skin: · Flush skin and hair with running water (and soap if available). · Remove any adhering solids with industrial skin cleansing cream. If aerosols, fumes or combustion products are inhaled: · Remove to fresh air. · Lay patient down. Keep warm and rested. NOTES TO PHYSICIAN
Treat symptomatically. · Heavy and persistent skin contamination over many years may lead to dysplastic changes. Pre-existing skin disorders may beaggravated by exposure to this product. · In general, emesis induction is unnecessary with high viscosity, low volatility products, i.e. most oils and greases. · High pressure accidental injection through the skin should be assessed for possible incision, irrigation and/or debridement. NOTE: Injuries may not seem serious at first, but within a few hours tissue may become swollen, discoloured and extremely painfulwith extensive subcutaneous necrosis. Product may be forced through considerable distances along tissue planes. For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:· Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure. · Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction,obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should beintubated. · Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury hasbeen reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excreteinhaled solvents, so that hyperventilation improves clearance. · A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detectthe presence of pneumothorax. · Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation tocatecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline asecond choice. · Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology]. continued. ROCOL CHAIN AND DRIVE SPRAY Chemwatch Material Safety Data Sheet Issue Date: 16-Jun-2006 CHEMWATCH 214465 XCC317SCP Version No:3 CD 2007/3 Page 3 of 7 Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA SMALL FIRE: · Water spray, dry chemical or CO2 LARGE FIRE: · Water spray or fog. FIRE FIGHTING · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. · If safe, switch off electrical equipment until vapour fire hazard removed. · Use water delivered as a fine spray to control fire and cool adjacent area. · DO NOT approach containers suspected to be hot. · Cool fire exposed containers with water spray from a protected location. · If safe to do so, remove containers from path of fire. · Equipment should be thoroughly decontaminated after use. FIRE/EXPLOSION HAZARD · Liquid and vapour are flammable. · Moderate fire hazard when exposed to heat or flame. · Vapour forms an explosive mixture with air. · Moderate explosion hazard when exposed to heat or flame. · Vapour may travel a considerable distance to source of ignition. · Heating may cause expansion or decomposition leading to violent rupture of containers. · Aerosol cans may explode on exposure to naked flame. · Rupturing containers may rocket and scatter burning materials. · Hazards may not be restricted to pressure effects. · May emit acrid, poisonous or corrosive fumes. · On combustion, may emit toxic fumes of carbon monoxide (CO). Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material. Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions. FIRE INCOMPATIBILITY Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. HAZCHEM: 2Y Personal Protective Equipment Gas tight chemical resistant suit. Section 6 - ACCIDENTAL RELEASE MEASURES EMERGENCY PROCEDURES MINOR SPILLS
Slippery when spilt. · Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Wear protective clothing, impervious gloves and safety glasses. · Shut off all possible sources of ignition and increase ventilation. · Wipe up. · If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated. · Undamaged cans should be gathered and stowed safely. MAJOR SPILLS
Slippery when spilt. · Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water courses· No smoking, naked lights or ignition sources. · Increase ventilation. · Stop leak if safe to do so. · Water spray or fog may be used to disperse / absorb vapour. · Absorb or cover spill with sand, earth, inert materials or vermiculite. · If safe, damaged cans should be placed in a container outdoors, away from ignition sources, until pressure has dissipated. · Undamaged cans should be gathered and stowed safely. · Collect residues and seal in labelled drums for disposal. continued. ROCOL CHAIN AND DRIVE SPRAY Chemwatch Material Safety Data Sheet Issue Date: 16-Jun-2006 CHEMWATCH 214465 XCC317SCP Version No:3 CD 2007/3 Page 4 of 7 Section 6 - ACCIDENTAL RELEASE MEASURES Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING · Avoid all personal contact, including inhalation. · Wear protective clothing when risk of exposure occurs. · Use in a well-ventilated area. · Prevent concentration in hollows and sumps. · DO NOT enter confined spaces until atmosphere has been checked. · Avoid smoking, naked lights or ignition sources. · Avoid contact with incompatible materials. · When handling, DO NOT eat, drink or smoke. · DO NOT incinerate or puncture aerosol cans. · DO NOT spray directly on humans, exposed food or food utensils. · Avoid physical damage to containers. · Always wash hands with soap and water after handling. · Work clothes should be laundered separately. · Use good occupational work practice. · Observe manufacturer's storing and handling recommendations. · Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. SUITABLE CONTAINER · Aerosol dispenser. · Check that containers are clearly labelled. STORAGE INCOMPATIBILITY Avoid reaction with oxidising agents. STORAGE REQUIREMENTS Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can. · Store in original containers in approved flammable liquid storage area. · DO NOT store in pits, depressions, basements or areas where vapours may be trapped. · No smoking, naked lights, heat or ignition sources. · Keep containers securely sealed. Contents under pressure. · Store away from incompatible materials. · Store in a cool, dry, well ventilated area. · Avoid storage at temperatures higher than 40 deg C. · Store in an upright position. · Protect containers against physical damage. · Check regularly for spills and leaks. · Observe manufacturer's storing and handling recommendations. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS Source
The following materials had no OELs on our records
• solvent naphtha petroleum, light aliphatic:
PERSONAL PROTECTION continued. ROCOL CHAIN AND DRIVE SPRAY Chemwatch Material Safety Data Sheet Issue Date: 16-Jun-2006 CHEMWATCH 214465 XCC317SCP Version No:3 CD 2007/3 Page 5 of 7 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATOR
No special equipment for minor exposure i.e. when handling small quantities. OTHERWISE: For potentially moderate or heavy exposures:· Safety glasses with side shields. · NOTE: Contact lenses pose a special hazard; soft lenses may absorb irritants and ALL lenses concentrate them. HANDS/FEET
No special equipment needed when handling small quantities. OTHERWISE:For potentially moderate exposures:Wear general protective gloves, eg. light weight rubber gloves. For potentially heavy exposures:Wear chemical protective gloves, eg. PVC. and safety footwear.
No special equipment needed when handling small quantities. OTHERWISE:· Overalls. · Skin cleansing cream. · Eyewash unit. · Do not spray on hot surfaces. ENGINEERING CONTROLS
General exhaust is adequate under normal conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit isessential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Supplied as an aerosol pack. Contents under PRESSURE.Contains highly flammablehydrocarbonpropellant.Black highly flammable liquid with a hydrocarbonsolvent odour; does not mix with water. Supplied as an aerosol pack. Contents under PRESSURE.Contains carbon dioxide propellant. PHYSICAL PROPERTIES Liquid. Gas. Does not mix with water. Floats on water. Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY · Elevated temperatures. · Presence of open flame. continued. ROCOL CHAIN AND DRIVE SPRAY Chemwatch Material Safety Data Sheet Issue Date: 16-Jun-2006 CHEMWATCH 214465 XCC317SCP Version No:3 CD 2007/3 Page 6 of 7 Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION · Product is considered stable. · Hazardous polymerisation will not occur. Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS
Possible risk of impaired fertility.
Vapours may cause dizziness or suffocation.
Harmful: danger of serious damage to health byprolonged exposure through inhalation.
Vapours may cause drowsiness and dizziness.
Limited evidence of a carcinogenic effect*.
May produce discomfort of the respiratory
May be harmful to the foetus/embryo*.
system*. Eye contact may produce serious damage*.
Cumulative effects may result followingexposure*.
Inhalation, skin contact and/or ingestion may
produce health damage*. * (limited evidence). TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
ILOEl: ILO Chemicals in the electronics industry that have toxic effects on reproduction: carbon dioxide
Section 12 - ECOLOGICAL INFORMATION Marine Pollutant:Not Determined Toxic to aquatic organisms,may cause long-term adverse effects in the aquatic environment. This material and its container must be disposed of as hazardouswaste. Avoid release to the environment. Refer to special instructions/safety data sheets. Section 13 - DISPOSAL CONSIDERATIONS · Consult State Land Waste Management Authority for disposal. · Discharge contents of damaged aerosol cans at an approved site. · Allow small quantities to evaporate. · DO NOT incinerate or puncture aerosol cans. · Bury residues and emptied aerosol cans at an approved site. Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GASHAZCHEM: 2Y
Air Transport IATA: ICAO/IATA Class: Maritime Transport IMDG: IMDG Class: continued. ROCOL CHAIN AND DRIVE SPRAY Chemwatch Material Safety Data Sheet Issue Date: 16-Jun-2006 CHEMWATCH 214465 XCC317SCP Version No:3 CD 2007/3 Page 7 of 7 Section 15 - REGULATORY INFORMATION POISONS SCHEDULE: None REGULATIONS Rocol Chain and Drive Spray (CAS: None): No regulationsapplicable solvent naphtha petroleum, light aliphatic (CAS: 64742-89-8)is found on the following regulatorylists; AustraliaHigh Volume Industrial Chemical List (HVICL) AustraliaInventoryof Chemical Substances(AICS) InternationalCouncil of Chemical Associations(ICCA) - High Production Volume List OECD RepresentativeList of High Production Volume (HPV) Chemicals carbon dioxide (CAS: 124-38-9) is found on the following regulatorylists; AustraliaExposure Standards AustraliaHigh Volume Industrial Chemical List (HVICL) AustraliaInventoryof Chemical Substances(AICS) CODEX General Standard for Food Additives(GSFA) - AdditivesPermitted for Use in Food in General, Unless Otherwise Specified, in Accordancewith GMP OECD RepresentativeList of High Production Volume (HPV) Chemicals No data available for mineral oil as CAS: Not avail. Section 16 - OTHER INFORMATION Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act,no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 16-Jun-2006 Print Date: 27-Sep-2007
BROMOTRIL ® 400 EC A selective emulsifiable concentrate herbicide for the ‘n Selektiewe emulgeerbare konsentraat onkruiddoder vir post emergent control of certain broadleaf weeds in the die na-opkom beheer van sekere breëblaaronkruide in ACTIVE INGREDIENT / AKTIEWE BESTANDDEEL Bromoxynil (nitrile) 400 g / ℓ Bromoksiniel (nitriel) as the octanoate as die oktanoaat B
Use of vancomycin silica stationary phase in packedPart IV: Enantiomer separation of fluoxetine andnorfluoxetine employing UV high sensitivityChimiche, Consiglio Nazionaledelle Ricerche, Area dellaRicerca di Roma, P.O. Box 10,The enantiomeric separation of the antidepressant drug fluoxetine and its mainmetabolite (norfluoxetine) was achieved by using capillary electrochromatographyemploying