Chemspray home pest control ant, spider & cockroach killer

Product Name: Chemspray Home Pest Control Ant, Spider & Cockroach Killer
Page: 1 of 6
This revision issued: May 2010
Amgrow Patrol Ant, Spider & Cockroach Killer
Section 1 - Identification of Chemical Product and Company
Amgrow Pty Ltd
Phone: (02) 9395 1200(Business hours)
PO Box 6390
Fax: (02) 9395 1241
Silverwater NSW 1811
Substance:
Permethrin in hydrocarbon solvent; added emulsifier. Trade Name:
Amgrow Patrol Ant, Spider & Cockroach Killer
Product Use:
Insecticide to control ants, spiders and cockroaches as described on the product label. Creation Date:
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Xn, Harmful. Hazardous according to the criteria of ASCC.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. However, this is a C1 Combustible Liquid and for storage meets the definition of Dangerous Goods. Risk Phrases: R43, R65. May cause sensitisation by skin contact. Harmful: May cause lung damage if
swallowed.
Safety Phrases: S2, S23, S28, S46, S62, S24/25. Keep out of reach of children. Do not breathe vapours
or spray mists. After contact with skin, wash immediately with plenty of soap and water. If swallowed,
contact a doctor or Poisons Information Centre immediately and show this container or label. If swallowed,
do not induce vomiting: seek medical advice immediately and show this MSDS. Avoid contact with skin and
eyes.
SUSDP Classification: S5
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Yellow liquid.
Odour: Characteristic hydrocarbon odour.
Major Health Hazards: Permethrin is harmful to non-harmful via the oral route, with a reported LD50 for
technical Permethrin in rats of 430 to 4000 mg/kg. Via the dermal route, it is not harmful, with a reported
dermal LD50 in rats of over 4000 mg/kg, and in rabbits of greater 2000 mg/kg. possible skin sensitiser, if
aspirated, may cause lung damage.
Potential Health Effects
Inhalation:
Short term exposure: Available data indicates that this product is not harmful. However product may be
mildly irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser,
once sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals
this reaction can be severe. In addition product may be irritating, but is unlikely to cause anything more
than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product may be irritating to eyes, but is unlikely to cause anything more than
mild transient discomfort.
Long Term exposure: No data for health effects associated with long term eye exposure.
MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Chemspray Home Pest Control Ant, Spider & Cockroach Killer
Page: 2 of 6
This revision issued: May 2010
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity
of this product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it
is very difficult to remove and can cause severe injury or death. However, this product may be irritating to
mucous membranes but is unlikely to cause anything more than transient discomfort.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
ASCC: No significant ingredient is classified as carcinogenic by ASCC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC:
Permethrin is Class 3 - unclassifiable as to carcinogenicity to humans. See the IARC website for further details. A web address has not been provided as addresses frequently change. Section 3 - Composition/Information on Ingredients
Ingredients
TWA (mg/m3) STEL (mg/m3)
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible. The ASCC TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly. Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this MSDS with you when you call. Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has
developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more
than about 30 minutes, seek medical advice.
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes
or until chemical is removed.
Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently
flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes
painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons
Information Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: This product is classified as a C1 combustible product. There is no risk of an
explosion from this product under normal circumstances if it is involved in a fire. Violent steam generation
or eruption may occur upon application of direct water stream on hot liquids. Vapours from this product are
heavier than air and may accumulate in sumps, pits and other low-lying spaces, forming potentially
explosive mixtures. They may also flash back considerable distances.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective
measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Chemspray Home Pest Control Ant, Spider & Cockroach Killer
Page: 3 of 6
This revision issued: May 2010
Flash point: >61°C
Upper Flammability Limit: 7.0%
Lower Flammability Limit: 0.6%
Autoignition temperature: No data.
Flammability Class: C1
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses.
Wear full protective clothing including eye/face protection. All skin areas should be covered. See below
under Personal Protection regarding Australian Standards relating to personal protective equipment.
Suitable materials for protective clothing include PVC, Nitrile. Eye/face protective equipment should
comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely
to build up in the cleanup area, we recommend that you use a respirator. It should be fitted with a type G
cartridge, suitable for agricultural chemicals. Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent
material. If spill is too large or if absorbent material is not available, try to create a dike to stop material
spreading or going into drains or waterways. Sweep up and shovel or collect recoverable product into
labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible
after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing
runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.
Full details regarding disposal of used containers, spillage and unused material may be found on the label.
If there is any conflict between this MSDS and the label, instructions on the label prevail. Ensure legality of
disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage
or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas.
Check Section 8 of this MSDS for details of personal protective measures, and make sure that those
measures are followed. The measures detailed below under "Storage" should be followed during handling
in order to minimise risks to persons using the product in the workplace. Also, avoid contact or
contamination of product with incompatible materials listed in Section 10.
Storage: Note that this product is combustible and therefore, for Storage, meets the definition of
Dangerous Goods in some states. If you store large quantities (tonnes) of such products, we suggest that
you consult your state's Dangerous Goods authority in order to clarify your obligations regarding their
storage.
Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out
of direct sunlight. Make sure that the product does not come into contact with substances listed under
"Incompatibilities" in Section 10. Some liquid preparations settle or separate on standing and may require
stirring before use. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial
Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
ASCC Exposure limits
TWA (mg/m3) STEL
Exposure limits have not been established by ASCC for any of the significant ingredients in this product. The ADI for permethrin is set at 0.05mg/kg/day. The corresponding NOEL is set at 5mg/kg/day. ADI means Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec 2005. No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Chemspray Home Pest Control Ant, Spider & Cockroach Killer
Page: 4 of 6
This revision issued: May 2010
Ventilation: No special ventilation requirements are normally necessary for this product. However make
sure that the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product
is being used.
Skin Protection: If you believe you may have a sensitisation to this product or any of its declared
ingredients, you should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron.
Make sure that all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials:
PVC, nitrile.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts
consult the Australian Standard mentioned above. Otherwise, not normally necessary.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Yellow
Boiling Point: Not
Freezing/Melting Point:
No specific data. Liquid at normal temperatures. Volatiles: No
Vapour Pressure: No
Vapour Density: No
Specific Gravity: 0.93
Water Solubility: Emulsifiable.
pH: No
Volatility: No
Odour Threshold: No
Evaporation Rate: No
Coeff Oil/water distribution: No
Autoignition temp: No
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if
you have any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool,
well-ventilated area out of direct sunlight.
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke.
Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness
of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Toxicity: Acute toxicity: Permethrin is harmful to non-harmful via the oral route, with a reported LD50 for
technical Permethrin in rats of 430 to 4000 mg/kg. Via the dermal route, it is not harmful, with a reported
dermal LD50 in rats of over 4000 mg/kg, and in rabbits of greater 2000 mg/kg. Permethrin caused mild
irritation of both the intact and abraded skin of rabbits. It also caused conjunctivitis when it was applied to
the eyes. The 4-hour inhalation LC50 for rats was greater than 23.5 mg/L, indicating practically no inhalation
toxicity. The toxicity of Permethrin is dependent on the ratio of the isomers present; the cis-isomer being
more toxic.
Chronic toxicity: No adverse effects were observed in dogs fed Permethrin at doses of 5 mg/kg/day for 90
days. Rats fed 150 mg/kg/day for 6 months showed a slight increase in liver weights. Very low levels of
Permethrin in the diet of chickens (0.1 ppm for 3 to 6 weeks after hatching) have been reported to suppress
immune system activity.
Reproductive effects: The fertility of female rats was affected when they received very high oral doses of
250 mg/kg/day of Permethrin during the 6th to 15th day of pregnancy. It is not likely that reproductive
effects will be seen in humans under normal circumstances.
MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Chemspray Home Pest Control Ant, Spider & Cockroach Killer
Page: 5 of 6
This revision issued: May 2010
Teratogenic effects: Permethrin is reported to show no teratogenic activity.
Mutagenic effects: Permethrin is reported to show no mutagenic activity.
Carcinogenic effects: The evidence regarding the carcinogenicity of Permethrin is inconclusive.
Organ toxicity: Permethrin is suspected of causing liver enlargement of the liver and nerve damage.
Effects on the immune system have been noted in animal studies.
Fate in humans and animals: Permethrin is efficiently metabolized by mammalian livers. Breakdown
products, or "metabolites," of Permethrin are quickly excreted and do not persist significantly in body
tissues. When Permethrin is administered orally to rats, it is rapidly metabolized and almost completely
eliminated from the body in a few days. Only 3 to 6% of the original dose was excreted unchanged in the
faeces of experimental animals. Permethrin may persist in fatty tissues, with half-lives of 4 to 5 days in
brain and body fat. Permethrin does not block, or inhibit, cholinesterase enzymes.
Section 12 - Ecological Information
Insufficient data to be sure of status.
Effects on birds: Permethrin is practically non-toxic to birds. The oral LD50 for a Permethrin formulation is
greater than 9900 mg/kg in mallard ducks, greater than 13,500 mg/kg in pheasants, and greater than
15,500 mg/kg in Japanese quail.
Effects on aquatic organisms: Aquatic ecosystems are particularly vulnerable to the impact of
Permethrin. A fragile balance exists between the quality and quantity of insects and other invertebrates that
serve as fish food. The 48-hour LC50 for rainbow trout is 0.0125 mg/L for 24 hours, and 0.0054 mg/L for 48
hours. The 48-hour LC50 in bluegill sunfish and salmon is 0.0018 mg/L. As a group, synthetic pyrethroids
were toxic to all estuarine species tested. They had a 96-hour LC50 of less than or equal to 0.0078 mg/L for
these species. The bioconcentration factor for Permethrin in bluefish is 715 times the concentrations in
water and is 703 in catfish. This indicates that the compound has a low to moderate potential to
accumulate in these organisms.
Effects on other organisms: Permethrin is extremely toxic to bees. Severe losses may be expected if
bees are present at treatment time, or within a day thereafter. Permethrin is also toxic to wildlife. It should
not be applied, or allowed to drift, to crops or weeds in which active foraging takes place.
Environmental Fate:
Breakdown in soil and groundwater: Permethrin is of low to moderate persistence in the soil
environment, with reported half-lives of 30 to 38 days. Permethrin is readily broken down, or degraded, in
most soils except organic types. Soil microorganisms play a large role in the degradation of Permethrin in
the soil. The addition of nutrients to soil may increase the degradation of Permethrin. It has been observed
that the availability of sodium and phosphorous decreases when Permethrin is added to the soil.
Permethrin is tightly bound by soils, especially by organic matter. Very little leaching of Permethrin has
been reported. It is not very mobile in a wide range of soil types. Because Permethrin binds very strongly to
soil particles and is nearly insoluble in water, it is not expected to leach or to contaminate groundwater.
Breakdown in water: The results of one study near estuarine areas showed that Permethrin had a half-life
of less than 2.5 days. When exposed to sunlight, the half-life was 4.6 days. Permethrin degrades rapidly in
water, although it can persist in sediments. There was a gradual loss of toxicity after Permethrin aged for
48 hours in sunlight at 0.05 mg/L in water.
Breakdown in vegetation: Permethrin is not phytotoxic, or poisonous, to most plants when it is used as
directed. Some injury has occurred on certain ornamental plants. No incompatibility has been observed
with Permethrin on cultivated plants. Treated apples, grapes, and cereal grains contain less than one
mg/kg of Permethrin at harvest time.
Section 13 - Disposal Considerations
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and
territory, so each user must refer to laws operating in their area. In some areas, certain wastes must be
tracked. The Hierarchy of Controls seems to be common - the user should investigate: Reduce, Reuse,
and Recycle and only if all else fails should disposal be considered. Note that properties of a product may
change in use, so that the following suggestions may not always be appropriate. The following may help
you in properly addressing this matter for this product. Special help is available for the disposal of
Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities,
and how to cleanse containers.
MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Chemspray Home Pest Control Ant, Spider & Cockroach Killer
Page: 6 of 6
This revision issued: May 2010
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are
necessary unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: liquid hydrocarbon, Permethrin are mentioned in the SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail Australian Inventory of Chemical Substances Australian Safety And Compensation Council CAS number
Chemical Abstracts Service Registry Number Hazchem Number
Emergency action code of numbers and letters that provide information to emergency services especially firefighters International Agency for Research on Cancer R-Phrase Risk
Standard for the Uniform Scheduling of Drugs & Poisons UN Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST. Please read all labels carefully before using product. This MSDS is prepared in accord with the ASCC document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright Kilford & Kilford Pty Ltd, May 2010 MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Source: http://amgrow.com.au/commerce/homegarden/ms29.pdf