SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product Name Chemical Name Common Name MSDS Number Chemical Family Chemical Formulation EPA Registration No.
For MEDICAL, TRANSPORTATION or Other EMERGENCY call 1-800-334-7577 24 hours/day For Product Information call 1-800-331-2867
Product Use Description Insecticide used to control insect pests in residential and recreational areas.
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS Concentration % by Weight Material Safety Data Sheet PERMANONE® READY-TO-USE INSECTICIDE
SECTION 3. HAZARDS IDENTIFICATION
NOTE: Please refer to Section 11 for detailed toxicological information. Emergency Overview
Caution! Prolonged or frequently repeated skin contact may cause allergic
reactions in some individuals. Wash thoroughly with soap and water after handling.
Physical State Appearance Routes of Exposure Immediate Effects
Avoid contact with eyes. Eye irritation is slight or negligible.
Avoid contact with skin or clothing. A slight irritant on brief contact.
Ingestion Inhalation
SECTION 4. FIRST AID MEASURES
Have the product container or label with you when calling a poison control center
Flush eyes with water at least 15 minutes. Get medical attention if eye irritation
Take off contaminated clothing. Rinse skin immediately with plenty of water for
15-20 minutes. Call a poison control center or doctor for treatment advice.
Ingestion
Call a poison control center or doctor for treatment advice. Do not induce
vomiting or give anything by mouth to an unconscious person.
Inhalation
Move person to fresh air. Seek medical attention if breathing difficulties occur.
Notes to physician
Contains petroleum distillates. May pose an aspiration pneumonia hazard.
This product contains a synthetic pyrethroid.
Material Safety Data Sheet PERMANONE® READY-TO-USE INSECTICIDE
SECTION 5. FIRE FIGHTING MEASURES
Flash Point Fire and Explosion
Combustible. Do not use or store near heat or open flame.
Suitable Extinguishing
Foam, Water, Dry chemical, Carbon dioxide (CO2)
Fire Fighting
Keep out of smoke. Cool exposed containers with water spray. Fight fire from
Instructions
upwind position. Wear full protective clothing and self-contained breathing
apparatus. Contain runoff to prevent entry into sewers or waterways. Equipment or materials involved in pesticide fires may become contaminated.
SECTION 6. ACCIDENTAL RELEASE MEASURES
General and Disposal
Keep unnecessary people away, isolate hazard area and deny entry. Avoid
contact with spilled product or contaminated surfaces.
Land Spill or Leaks
Avoid breathing vapors and skin contact. Wear proper protective equipment.
Dike contaminated area with absorbent granules, soil, sand, etc. Large Spill: Material should be recovered. Small spills can be absorbed with absorbent granules, spill control pads, or any absorbent material. Carefully sweep up absorbed spilled material. Place in covered container for reuse or disposal. Scrub contaminated area with soap and water. Use dry absorbent material such as clay granules to absorb and collect wash solution for proper disposal. Contaminated soil may have to be removed and disposed. Do not allow material to enter streams, sewers, or other waterways or contact vegetation.
SECTION 7. HANDLING AND STORAGE
Handling Procedures Storing Procedures
Store upright at room temperature. Avoid exposure to extreme temperatures.
Do not contaminate water, food, or feed by storage or disposal.
Work/Hygienic
Wash hands thoroughly with soap and water after handling and before eating,
Procedures
drinking, chewing gum, using tobacco, or using the toilet.
Remove and wash contaminated clothing before re-use.
Material Safety Data Sheet PERMANONE® READY-TO-USE INSECTICIDE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls
Use only with adequate ventilation. Maintain exposure levels below the exposure
limit through the use of general and local exhaust ventilation.
Eye/Face Protection Hand Protection Body Protection
Wear long-sleeved shirt and long pants and shoes plus socks.
Respiratory Protection
When respirators are required, select NIOSH/MSHA approved equipment based
on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations.
Exposure Limits
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Physical State Specific Gravity Solubility (in water)
SECTION 10. STABILITY AND REACTIVITY
Chemical Stability
This material is stable under normal handling and storage conditions described
Conditions to Avoid Incompatibility Hazardous Products of Decomposition Material Safety Data Sheet PERMANONE® READY-TO-USE INSECTICIDE Hazardous Polymerization (Conditions to avoid)
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity studies have not been performed on this product as formulated. The acute toxicity data provided is bridged from a similar Permanone Ready-To-Use formulation. Symptoms observed in studies with laboratory animals exposed at or near the LD50/LC50 included increased urination,decreased activity, nasal discharge, salivation, bulging eyes and erect body hair. Extremely high doses have caused convulsions. Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity LC50: > 5.22 mg/l 4 h
1-hr exposure (extrapolated from 4-hr LC50): > 20.88 mg/l (for DOT purposes)
Skin Irritation Eye Irritation Sensitization Chronic Toxicity
A statistically significant increase in the incidence of lung and liver tumors was
observed in female mice receiving diets containing 375 and 750 mg/kg/day of permethrin technical over 85 weeks. A statistically significant increase in the number of benign liver tumors appeared in mice fed piperonyl butoxide technical at doses which far exceed any anticipated daily human intake. Independent and industry toxicological experts who have reviewed the data agree that the findings of the study do not indicate a health risk to human beings.
Assessment Carcinogenicity Material Safety Data Sheet PERMANONE® READY-TO-USE INSECTICIDE
SECTION 12. ECOLOGICAL INFORMATION
Environmental
This product is highly toxic to fish. Avoid direct application or spray drift to water
Precautions
surfaces. Do not apply directly to water, to areas where surface water is present
or to intertidal areas below the mean high water mark. Drift and runoff from treated areas may be hazardous to fish/aquatic organisms in adjacent sites. Apply this product only as specified on the label. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment washwater.
This product is highly toxic to bees exposed to direct treatment of residues on blooming crops or weeds. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area.
SECTION 13. DISPOSAL CONSIDERATIONS
General Disposal
Pesticide Disposal: Wastes resulting from the use of this product may be
Guidance
disposed of on site or at an approved waste disposal facility.
Container Disposal
Metal Containers: Triple rinse or equivalent. Then offer for recycling or
reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities.
Plastic Containers: Triple rinse or equivalent. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by incineration or, if allowed by State and Local authorities, by burning. If burned, stay out of smoke.
Refillable Container: Replace the dry disconnect cap if applicable, and seal all openings which have been opened during use. Return empty container to a collection site designated by Bayer.
RCRA Classification
SECTION 14. TRANSPORT INFORMATION
DOT CLASSIFICATION: Not regulated for Domestic Surface Transportation FREIGHT CLASSIFICATION: Insecticides or Fungicides, N.O.I., other that poison
Material Safety Data Sheet PERMANONE® READY-TO-USE INSECTICIDE
SECTION 15. REGULATORY INFORMATION
EPA Registration No.
US Federal Regulations TSCA list TSCA 12b export notification SARA Title III - section 302 - notification and information SARA Title III - section 313 - toxic chemical release reporting US States Regulatory Reporting CA Prop65
This product does not contain any substances known to the State of California to cause cancer.
This product does not contain any substances known to the State of California to cause reproductive harm.
US State right-to-know ingredients
Canadian Regulations Canadian Domestic Substance List
Environmental Clean Water Section 307 Priority Pollutants Safe Drinking Water Act Maximum Contaminant Levels International Regulations EU Classification
Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
Material Safety Data Sheet PERMANONE® READY-TO-USE INSECTICIDE European Inventory of Existing Commercial Substances (EINECS)
SECTION 16. OTHER INFORMATION
MSDS REVISION INDICATOR: Company address change.
This information is provided in good faith but without express or implied warranty. Buyer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer AG. Bayer Environmental Science
Short-Term and Long-Term Effects of Bisoprolol on Chronic Heart Failure Related to Rheumatic Heart Disease and Atrial Fibrillation Maoqin Shu, MD, Ruixia Xi, PhD, Ping Zhang, MD, Guoxiang He, PhD, Zhiyuan Song, MD, Luxiang Chi, MD, and Guoqiang Zhuang, PhD ABSTRACT treatment group showed improved NYHA class and exercise Objective: We investigated whether a selective beta block
Volume 5. Wilhelmine Germany and the First World War, 1890-1918 Germany’s Industrial Leaders on War Aims (1915) Annexations were part of the Right’s underlying assumptions about German victory. In the occupied territories to the West, the opportunities for exploitation were lavish, ranging from rich reserves in raw materials to modern plant capacity. Here, important representatives of Ger